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Molybdenum carbonyl assisted reductive tetramerization of CO by activated magnesium(<scp>i</scp>) compounds: squarate dianion vs. metallo-ketene formation
- Source :
- Chemical Science. 14:5188-5195
- Publication Year :
- 2023
- Publisher :
- Royal Society of Chemistry (RSC), 2023.
-
Abstract
- The reductive tetramerisation of CO by Lewis base activated dimagnesium(i) compounds, in the presence of Mo(CO)6, led to the competitive formation of magnesium squarate and metallo-ketene complexes (see picture).
- Subjects :
- General Chemistry
Subjects
Details
- ISSN :
- 20416539 and 20416520
- Volume :
- 14
- Database :
- OpenAIRE
- Journal :
- Chemical Science
- Accession number :
- edsair.doi...........b60d5b510b766be6d475fe630562f10e
- Full Text :
- https://doi.org/10.1039/d3sc01487h