Back to Search Start Over

Cyclopentadienyl ring metalation in cyclopentadienyliron carbonyl complexes

Authors :
D. N. Kursanov
V. N. Setkina
T. Yu. Orlova
V. F. Sizoi
Source :
Journal of Organometallic Chemistry. 252:201-204
Publication Year :
1983
Publisher :
Elsevier BV, 1983.

Abstract

The cyclopentadienyl ligands in Cp(CO)2FePh, Cp(CO)2FeCH2Ph and [Cp(CO)2Fe]2 were metalated by BuLi in THF at −78°C. With Cp(CO)2FePh it was possible to employ the reaction for the synthesis of cyclopentadienyl carbonyl complexes substituted on the Cp ligands.

Details

ISSN :
0022328X
Volume :
252
Database :
OpenAIRE
Journal :
Journal of Organometallic Chemistry
Accession number :
edsair.doi...........b374a3d07aa03bed28991a6bacebe951
Full Text :
https://doi.org/10.1016/0022-328x(83)80084-9