Palladium(II)-catalyzed hydroesterification of enol esters: Remarkable α-substituent effect upon regioselectivity

Authors :: Sadayuki Mori
Y. Oida
Koichi Komatsu
Kiyoshi Kudo
Nobuyuki Sugita
Source :: Reaction Kinetics & Catalysis Letters. 59:29-33
Publication Year :: 1996
Publisher :: Springer Science and Business Media LLC, 1996.
Abstract: Pd(II)-catalyzed hydroesterification of various enol esters smoothly proceeded upon the combined use of pressurized carbon monoxide and methanol to give the α-or β-acetoxy esters with the regioselectivity highly depending on the size of the α-substituent.

Subjects :: Combined use
Substituent
chemistry.chemical_element
Regioselectivity
Enol
Catalysis
chemistry.chemical_compound
chemistry
Organic chemistry
Methanol
Physical and Theoretical Chemistry
Palladium
Carbon monoxide

Full Text Access

Tools