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Commentary concerning 'measurement and correlation of solubility and solution thermodynamics of 1,3-dimethylurea in different solvents from T = (288.15 to 328.15) K'

Authors :
Renjie Xu
Jiao Chen
Gaoquan Chen
Hongkun Zhao
Min Zheng
Source :
The Journal of Chemical Thermodynamics. 129:141-144
Publication Year :
2019
Publisher :
Elsevier BV, 2019.

Abstract

Errors were discovered regarding the published equation coefficients of Zhu and co-workers [J. Chem. Thermodynamics 97 (2016) 9–16] for mathematically describing the solubility behavior of 1,3-dimethylurea in different pure solvents using the Wilson model. Larger differences were found between our back-calculated data and those reported in the authors’ published paper. The expression of Wilson model was corrected and the equation parameters were re-regressed. In addition, the thermodynamic functions of mixing such as change of mixing Gibbs energy, mixing enthalpy and mixing entropy of mixing were re-calculated.

Details

ISSN :
00219614
Volume :
129
Database :
OpenAIRE
Journal :
The Journal of Chemical Thermodynamics
Accession number :
edsair.doi...........b2f366bdb1b1b178647e7c110a25d5c9
Full Text :
https://doi.org/10.1016/j.jct.2018.09.005