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Commentary concerning 'measurement and correlation of solubility and solution thermodynamics of 1,3-dimethylurea in different solvents from T = (288.15 to 328.15) K'
- Source :
- The Journal of Chemical Thermodynamics. 129:141-144
- Publication Year :
- 2019
- Publisher :
- Elsevier BV, 2019.
-
Abstract
- Errors were discovered regarding the published equation coefficients of Zhu and co-workers [J. Chem. Thermodynamics 97 (2016) 9–16] for mathematically describing the solubility behavior of 1,3-dimethylurea in different pure solvents using the Wilson model. Larger differences were found between our back-calculated data and those reported in the authors’ published paper. The expression of Wilson model was corrected and the equation parameters were re-regressed. In addition, the thermodynamic functions of mixing such as change of mixing Gibbs energy, mixing enthalpy and mixing entropy of mixing were re-calculated.
- Subjects :
- Chemistry
Enthalpy
Thermodynamics
02 engineering and technology
Entropy of mixing
Dimethylurea
010402 general chemistry
01 natural sciences
Atomic and Molecular Physics, and Optics
0104 chemical sciences
Gibbs free energy
symbols.namesake
chemistry.chemical_compound
020401 chemical engineering
symbols
General Materials Science
0204 chemical engineering
Physical and Theoretical Chemistry
Solubility
Mixing (physics)
Wilson model
Subjects
Details
- ISSN :
- 00219614
- Volume :
- 129
- Database :
- OpenAIRE
- Journal :
- The Journal of Chemical Thermodynamics
- Accession number :
- edsair.doi...........b2f366bdb1b1b178647e7c110a25d5c9
- Full Text :
- https://doi.org/10.1016/j.jct.2018.09.005