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Diaquabis(5-carboxy-2-propyl-1H-imidazole-4-carboxylato-κ2N3,O4)manganese(II) 3.5-hydrate
- Source :
- Acta Crystallographica Section E Structure Reports Online. 66:m1096-m1097
- Publication Year :
- 2010
- Publisher :
- International Union of Crystallography (IUCr), 2010.
-
Abstract
- In the title complex, [Mn(C8H9N2O4)2(H2O)2]·3.5H2O, the MnII cation is six-coordinated by two N,O-bidentate H2pimda− ligands (H2pimda− = 5-carb­oxy-2-propyl-1H-imidazole-4-carboxyl­ate) and two water mol­ecules in a distorted octa­hedral environment. The complete solid-state structure can be described as a three-dimensional supra­molecular framework stabilized by a wide range of O—H⋯O and N—H⋯O hydrogen bonds. The propyl groups of H2pimda− are disordered over two sets of sites with refined occupancies of 0.759 (5):0.241 (5) and 0.545 (7):0.455 (7).
Details
- ISSN :
- 16005368
- Volume :
- 66
- Database :
- OpenAIRE
- Journal :
- Acta Crystallographica Section E Structure Reports Online
- Accession number :
- edsair.doi...........b2c0e848c6b4a991c6d98812dd417337
- Full Text :
- https://doi.org/10.1107/s1600536810031612