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Homogenous Dispersion of MoS2 Nanosheets in Polyindole Matrix at Air–Water Interface Assisted by Langmuir Technique

Authors :
Rajiv Prakash
Richa Mishra
Ravi Prakash Ojha
Narsingh R. Nirala
Rajiv K. Pandey
Source :
Langmuir. 33:13572-13580
Publication Year :
2017
Publisher :
American Chemical Society (ACS), 2017.

Abstract

Two-dimensional (2D) inorganic layered materials when embedded in organic polymer matrix exhibit exotic properties that are grabbing contemporary attention for various applications. Here, nanosheet morphology of molybdenum disufide (MoS2) synthesized via one-pot facile hydrothermal reaction are exfoliated in benign aqueous medium in the presence of indole to obtain a stable dispersion. These exfoliated nanosheets then act as host to template the controlled polymerization of indole. The preassembled MoS2-polyindole (MoS2–PIn) nanostructures are reorganized at the air–water interface using the Langmuir method to facilitate maximum interfacial interaction between nanosheet and polymer. This report emphasizes large area, homogeneous dispersion of uniform-sized MoS2 nanosheets (40–60 nm diameter) in the PIn matrix and the formation of stable and uniform film via the Langmuir–Schaefer (LS) method. These self-assembled, MoS2 decorated PIn LS films are characterized using atomic force microscopy (AFM) and transmi...

Details

ISSN :
15205827 and 07437463
Volume :
33
Database :
OpenAIRE
Journal :
Langmuir
Accession number :
edsair.doi...........b1ca9146883aa0384beb138fe59bc51f
Full Text :
https://doi.org/10.1021/acs.langmuir.7b03019