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Reactions of Carbohydrazide and 1,5-Bis(Carbohydrazones) with Antimony(III) Chloride

Authors :
R. Rastogi
Ramesh N. Kapoor
G. K. Parashar
Source :
Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry. 15:1061-1071
Publication Year :
1985
Publisher :
Informa UK Limited, 1985.

Abstract

Antimony trichloride when reacted with carbohydrazide and 1,5-bis(carbohydrazones), yields addition complexes of the type Sb(L)nCl3 (where n = 1,2) and Sb(L′)Cl3 as well as [Sb(L′)2Cl2] Cl (where L = carbohydrazide, L′ = 1,5-bis (carbohydrazones) of 2-hydroxybenzaldehyde, 4-hydroxy-3-methoxybenzaldehyde, 2-hydroxyphenylmethylketone and 2,4-dihydroxyphenylmethylketone). These complexes are characterised on the basis of infra-red spectra, electronic spectra and conductivity measurements in addition to elemental analysis. These indicate that the ligands are coordinated to antimony(III) in a bidentate manner.

Details

ISSN :
15322440 and 00945714
Volume :
15
Database :
OpenAIRE
Journal :
Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry
Accession number :
edsair.doi...........b14f7e4b822b2c9617c6a98c5f181887