Determination of configuration of products of nucleophilic addition to activated acetylenes by the NMR method

Authors :: N. L. Zaichenko
Yu. I. El'natanov
I. I. Chervin
V. N. Voznesenskii
R. G. Kostyanovskii
Source :: Bulletin of the Academy of Sciences of the USSR Division of Chemical Science. 37:663-666
Publication Year :: 1988
Publisher :: Springer Science and Business Media LLC, 1988.
Abstract: It was shown that the stereospecificity of SSCC3 C,H trans > 3J C,H cis is applicable as a configurational test for di- and trisubstituted alkenes R2E(Y)C=C(X)H with various heteroatomic substituents (E=N, P, S) and activating groups (X=CO2Alk, CN at Y=H, and X=Y=CO2Alk, CN, CF3).

Subjects :: chemistry.chemical_classification
chemistry.chemical_compound
Stereospecificity
Nucleophilic addition
Acetylene
Chemistry
Stereochemistry
Alkene
General Chemistry

ISSN :: 15739171 and 05685230
Volume :: 37
Database :: OpenAIRE
Journal :: Bulletin of the Academy of Sciences of the USSR Division of Chemical Science
Accession number :: edsair.doi...........b11088c87961084ff22f213ddab3d1c9
Full Text :: https://doi.org/10.1007/bf01455472

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