Microfluidic Aluminum-air Cell with Methanol-based Anolyte

Aluminum-air cell, with trivalence redox couples, attracts a lot of interest to break the capacity limitation of conventional batteries in pursuit of higher mobility for portable devices. In order to overcome the self-discharge issue of aluminum, a microfluidic aluminum-air cell working with methanol-based anolyte was developed in this work. The operation feasibility of this membraneless cell was first proved. Then, the influences of electrolyte concentration and water content in the methanol-based anolyte on cell performances were investigated. Experimentally, a high discharge capacity density of 2507 mAh/g was achieved at a low current of 0.015 mA.