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A novel lithium ionic cluster at the surface of magnesia

Authors :
Adriano Zecchina
Damien Martin Murphy
Elio Giamello
Source :
The Journal of Physical Chemistry. 97:1739-1742
Publication Year :
1993
Publisher :
American Chemical Society (ACS), 1993.

Abstract

A novel paramagnetic ionic cluster containing three lithium ions (likely Li 3 2+ ) has been obtained upon treatment of the dehydrated MgO surface with vapors of lithium. The corresponding EPR spectrum is characterized by g=2.0011 and a hyperfine splitting of 8.26 G (1 G=0.1 mT).

Details

ISSN :
15415740 and 00223654
Volume :
97
Database :
OpenAIRE
Journal :
The Journal of Physical Chemistry
Accession number :
edsair.doi...........b02abbbd997393f943f0554989a02da7
Full Text :
https://doi.org/10.1021/j100111a005