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Convenient method for preparation of aryl sulfinates from arenes and DABSO as the SO2 surrogates

Authors :
Xubin Zhang
Tianlei Wang
Ren Yanfei
Fumin Wang
Jinghua Shen
Botao Wu
Tianting Pang
Source :
Tetrahedron Letters. 59:1183-1187
Publication Year :
2018
Publisher :
Elsevier BV, 2018.

Abstract

A safe and efficient protocol for the synthesis of aryl sulfinates from arenes and 1,4-diazabicyclo[2,2,2]octane bis(sulfur dioxide) (DABSO) under mild conditions is described. Through in situ infrared spectroscopic studies, a plausible mechanism for the sulfination reaction is proposed as well.

Details

ISSN :
00404039
Volume :
59
Database :
OpenAIRE
Journal :
Tetrahedron Letters
Accession number :
edsair.doi...........afe7cab574f83c2ccc56f9aa819424b3
Full Text :
https://doi.org/10.1016/j.tetlet.2018.01.081