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Synthesis and characterization of mononuclear bis(para-substituted phenolato)oxomolybdenum(V) complexes: dependence of the molecular properties upon remote substituent effects
- Source :
- Inorganic Chemistry. 32:4106-4110
- Publication Year :
- 1993
- Publisher :
- American Chemical Society (ACS), 1993.
-
Abstract
- Bis(para-substituted phenolato)oxomolybdenum(V) complexes with the general formula LMoO(OC 6 H 4 X) 2 , where L=hydrotris(3,5-dimethyl-1-pyrazolyl)borate and X=Me, Et, OMe, OEt, OH, F, Cl, Br, I, and CN, have been prepared and characterized by elemental analyses, mass spectrometry, and IR, EPR, and UV-vis-near-IR spectrospy. The energies of both the ligand-field and the lowest-energy charge-transfer bands depend upon the σ p values of the para substituents (X) on the phenolato ligands
- Subjects :
- Chemistry
Stereochemistry
Substituent
chemistry.chemical_element
Mass spectrometry
law.invention
Characterization (materials science)
Inorganic Chemistry
Crystallography
chemistry.chemical_compound
law
X-ray crystallography
Molecule
Physical and Theoretical Chemistry
Electron paramagnetic resonance
Boron
Subjects
Details
- ISSN :
- 1520510X and 00201669
- Volume :
- 32
- Database :
- OpenAIRE
- Journal :
- Inorganic Chemistry
- Accession number :
- edsair.doi...........ae3e7cfa3d5abd45214815816eddff84