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ChemInform Abstract: Formation of Allenyl Cations by Photolysis of Triarylchloroallenes

Authors :
Shinjiro Kobayashi
Hiroki Taniguchi
Sumiya Miyake
Tsugio Kitamura
Source :
Chemischer Informationsdienst. 17
Publication Year :
1986
Publisher :
Wiley, 1986.

Abstract

Irradiation of triarylchloroallenes in methanol afforded 1,3,3-triaryl-3-methoxypropynes, suggesting the intervention of triarylallenyl cations. Irradiation of triphenylchloroallene in ethanol and 2-propanol gave the similar results but the irradiation in t-butyl alcohol gave only the products from triphenylallenyl radical.

Details

ISSN :
00092975
Volume :
17
Database :
OpenAIRE
Journal :
Chemischer Informationsdienst
Accession number :
edsair.doi...........adae855b531382a6a7aa2c0a53d3ec2d
Full Text :
https://doi.org/10.1002/chin.198602170