A 21 micron emission feature in four proto-planetary nebulae

The discovery of an unidentified emission feature at 21 microns in the LRS spectra of four IRAS sources is reported. These objects all show large FIR excesses due to a circumstellar dust envelope surrounding a carbon-rich central star and are likely to be in the evolutionary phase between the asymptotic giant branch and planetary nebula stages. The strength of the feature and the carbon richness of the objects suggest that this feature is due to the bending mode of a transient carbon-bearing molecule.