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ChemInform Abstract: N-Acyl-5,5-dimethyl-oxazolidin-2-ones as Latent Aldehyde Equivalents

Authors :
Andrew D. Smith
Rebecca L. Nicholson
Stephen G. Davies
Steven D. Bull
Jordi Bach
Hitesh J. Sanganee
Source :
ChemInform. 30
Publication Year :
2010
Publisher :
Wiley, 2010.

Abstract

N -acyl-5,5-dimethyl-oxazolidin-2-ones can function as versatile latent aldehyde equivalents - reductive cleavage with DIBAL-H affords aldehydes in good yield, while tandem DIBAL-H/Wittig methodology affords α,β-unsaturated esters.

Details

ISSN :
15222667 and 09317597
Volume :
30
Database :
OpenAIRE
Journal :
ChemInform
Accession number :
edsair.doi...........ac3137c821ff5d16f2f549e7bef162d4
Full Text :
https://doi.org/10.1002/chin.199950062