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A novel TiO2/graphite felt photoanode assisted electro-Fenton catalytic membrane process for sequential degradation of antibiotic florfenicol and elimination of its antibacterial activity
- Source :
- Chemical Engineering Journal. 391:123503
- Publication Year :
- 2020
- Publisher :
- Elsevier BV, 2020.
-
Abstract
- Antibiotics, especially halogenated antibiotics, which account for nearly 40% of the total antibiotics in China, pose great environmental risks; however, the superior stability of C–F bond and low concentrations hinder their degradation, indicating the need for developing of highly efficient treatment technologies. There is an additional concern that some degradation products could be as active/toxic as or even more than their parent compound. The stable C–F bond can be relative easily cleaved by UV light irradiation, which could come from sunlight. Herein, a novel UV-driven electro-Fenton catalytic membrane (UV-EFCM) filtration system that favors resistance elimination and efficient degradation of low-concentration antibiotics is proposed for the first time. The photo-electrochemical/electro-Fenton (PEC/EF) coupling reaction is synchronously conducted in a sequential filtration system. Almost complete degradation and high mineralization (78.4 ± 9.1%) of florfenicol were achieved at a concentration of as low as 14 µM with the hydraulic retention time of 0.98 h during the UV-EFCM filtration system. Complete elimination of its antibacterial activity, and significant defluorination improvement (56 ± 3.6%) compared to electro-Fenton filtration process (11 ± 5.3%) were achieved due to the prior cleavage of the stable C–F bond with antibiotic potency under UV light pretreatment. This study thus proposes a novel UV-EFCM filtration system, which couples PEC and EF with a potential to tackle the environmental problems associated with antibiotic pollution.
- Subjects :
- Florfenicol
Hydraulic retention time
medicine.drug_class
General Chemical Engineering
Antibiotics
02 engineering and technology
General Chemistry
010402 general chemistry
021001 nanoscience & nanotechnology
01 natural sciences
Combinatorial chemistry
Industrial and Manufacturing Engineering
Coupling reaction
0104 chemical sciences
law.invention
chemistry.chemical_compound
chemistry
law
medicine
Environmental Chemistry
Degradation (geology)
Graphite
0210 nano-technology
Antibacterial activity
Filtration
Subjects
Details
- ISSN :
- 13858947
- Volume :
- 391
- Database :
- OpenAIRE
- Journal :
- Chemical Engineering Journal
- Accession number :
- edsair.doi...........abe883773c027a13a4755906fdd0c15c