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The Magic Salt Effects of Sodium Hexafluorophosphate

Authors :
Jaime Ruiz
Marie-hélène
Didier Astruc
Françoise Moulines
Delville-desbois
Jean-René Hamon
Marc Lacoste
Source :
Phosphorus, Sulfur, and Silicon and the Related Elements. 87:11-22
Publication Year :
1994
Publisher :
Informa UK Limited, 1994.

Abstract

The Na+PF6− salt changes the course of reactions between neutral or ionic substrates. Examples of reactions include superoxide radical chemistry, disproportionation, and C[sbnd]H and C[sbnd]O bond activation. This special salt effect is usually quantitative and sometimes catalytic. When compared to other salts, Na+PF6− by far gives the most spectacular results, due to the small size of Na+ as compared to large organometallic cations.

Details

ISSN :
15635325 and 10426507
Volume :
87
Database :
OpenAIRE
Journal :
Phosphorus, Sulfur, and Silicon and the Related Elements
Accession number :
edsair.doi...........ab926ffdd6bd6352b070b6d214a03c60