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SECONDARY DEUTERIUM ISOTOPE EFFECTS IN CHEMICAL AND BIOCHEMICAL REACTIONS*

Authors :
V. J. Shiner
R. R. Hiatt
Henry R. Mahler
R. H. Baker
Source :
Annals of the New York Academy of Sciences. 84:583-595
Publication Year :
2006
Publisher :
Wiley, 2006.

Abstract

Information concerning the secondary isotope rate effect caused by deuterium substitution on the carbon atom next to the reaction center in carbonium ion type reactions is reviewed, and then some other examples of secondary deuterium isotope effects in organic chemistry are summarized. Some new results on isotope effects in some enzyme-catalyzed hydrogen-transfer reactions are also given. (P.C.H.)

Subjects

Subjects :
inorganic chemicals
Photosynthetic reaction centre
Isotope
General Neuroscience
Radiochemistry
chemistry.chemical_element
General Biochemistry, Genetics and Molecular Biology
Ion
History and Philosophy of Science
Deuterium
chemistry
Carbonium ion
Kinetic isotope effect
Biochemical reactions
Carbon

Details

ISSN :
00778923
Volume :
84
Database :
OpenAIRE
Journal :
Annals of the New York Academy of Sciences
Accession number :
edsair.doi...........ab5bc2f09f6543708ad45408c2f88069
Full Text :
https://doi.org/10.1111/j.1749-6632.1960.tb39091.x
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