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Enhancing the performance of CsPbIBr2 solar cells through zinc halides doping

Authors :
Lun Zhang
Jun Zhu
Yinyan Xu
Akang Yang
Mei Lyu
Zhu Chen
Qian Wang
Ru Zhou
Hongbo Lu
Source :
Synthetic Metals. 281:116918
Publication Year :
2021
Publisher :
Elsevier BV, 2021.

Abstract

B-site doping is an effective strategy to improve the performance of inorganic perovskite solar cells. Zinc halides (ZnX2, X I, Br, Cl) doped CsPbIBr2 solar cells were prepared by simply introducing ZnX2 salts into the precursor solution for one step spin-coating process. The doped inorganic perovskite films exhibit enhanced crystallinity and improved surface morphology. More over, the photoluminescence and single-carrier device characterizations confirm that the internal defect density of CsPbIBr2 films decreases remarkably after ZnX2 doping and the non-radiative recombination is suppressed. The CsPbIBr2 solar cells based on the ZnI2 doped films achieve a champion efficiency of 8.15%, outperforming that (6.93%) of the pristine counterpart.

Details

ISSN :
03796779
Volume :
281
Database :
OpenAIRE
Journal :
Synthetic Metals
Accession number :
edsair.doi...........aaba26e7f047f6563a124a90a7a5a151
Full Text :
https://doi.org/10.1016/j.synthmet.2021.116918