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Moisture tolerant cationic RAFT polymerization of vinyl ethers

Authors :
Shelby L. Shankel
Tristan H. Lambert
Brett P. Fors
Source :
Polymer Chemistry. 13:5974-5979
Publication Year :
2022
Publisher :
Royal Society of Chemistry (RSC), 2022.

Abstract

Cationic RAFT of vinyl ethers was performed without reagent purification and under ambient conditions by utilizing a PCCP acid initiator with a HBD catalyst. Despite inherent nucleophiles, the system retained high chain end fidelity and modularity.

Details

ISSN :
17599962 and 17599954
Volume :
13
Database :
OpenAIRE
Journal :
Polymer Chemistry
Accession number :
edsair.doi...........aaa1362b3b878eb49dadafee5624e98a
Full Text :
https://doi.org/10.1039/d2py00780k