New Method for the Preparation of Octathiotetraphosphetanes on the Basis of Elemental Phosphorus and Sulfur: Structure and Properties

Authors :: Elena E. Zvereva
A.E. Vandyukov
Valery I. Kovalenko
E. K. Badeeva
Oleg G. Sinyashin
Elena V. Platova
L. I. Kursheva
Elvira S. Batyeva
Source :: Phosphorus, Sulfur, and Silicon and the Related Elements. 186:852-853
Publication Year :: 2011
Publisher :: Informa UK Limited, 2011.
Abstract: New octathiotetraphosphetane ammonium salts are obtained based on the reaction of white phosphorus (Р4) and elemental sulfur with aliphatic mercaptans in the presence of amines (morpholine, methylmorpholine, pyrrolidine, and N,N-dimethylbenzylamine). The salts of octathiotetraphosphetane are characterized by IR/Raman spectroscopy. Several common IR and Raman bands can be used as structural markers for establishing the structures of [P4S8]4− anion in new compounds.

Subjects :: White Phosphorus
Phosphorus
Organic Chemistry
Inorganic chemistry
chemistry.chemical_element
Biochemistry
Sulfur
Pyrrolidine
Ion
Inorganic Chemistry
chemistry.chemical_compound
symbols.namesake
chemistry
Morpholine
symbols
Ammonium
Raman spectroscopy

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