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New Method for the Preparation of Octathiotetraphosphetanes on the Basis of Elemental Phosphorus and Sulfur: Structure and Properties
- Source :
- Phosphorus, Sulfur, and Silicon and the Related Elements. 186:852-853
- Publication Year :
- 2011
- Publisher :
- Informa UK Limited, 2011.
-
Abstract
- New octathiotetraphosphetane ammonium salts are obtained based on the reaction of white phosphorus (Р4) and elemental sulfur with aliphatic mercaptans in the presence of amines (morpholine, methylmorpholine, pyrrolidine, and N,N-dimethylbenzylamine). The salts of octathiotetraphosphetane are characterized by IR/Raman spectroscopy. Several common IR and Raman bands can be used as structural markers for establishing the structures of [P4S8]4− anion in new compounds.
Details
- ISSN :
- 15635325 and 10426507
- Volume :
- 186
- Database :
- OpenAIRE
- Journal :
- Phosphorus, Sulfur, and Silicon and the Related Elements
- Accession number :
- edsair.doi...........a9c7ef54fcc42cb9aed6c50f3e3724d1