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Anticorrosive behavior of epoxy coating modified with hydrophobic nano-silica on phosphatized carbon steel
- Source :
- Progress in Organic Coatings. 151:106051
- Publication Year :
- 2021
- Publisher :
- Elsevier BV, 2021.
-
Abstract
- Corrosion existing in many fields brings lots of troubles to our life. In this work, epoxy coatings modified by hydrophobic nano-silica and hydrophilic nano-silica were fabricated to provide corrosion protection for phosphatized Q235 carbon steel. The traditional epoxy coating was prepared by the polymerization of trimethylolpropane triglycidyl ether and diethylenetriamine. The modified epoxy coating was fabricated by the polymerization and mixing of trimethylolpropane triglycidyl ether, diethylenetriamine and nano-silica. The microscopic morphologies of various epoxy coatings were investigated by SEM. Wettability of epoxy coatings was measured by static contact angle measurement instrument. Thermal stability was tested by thermo gravimetric analyzer. Corrosion behaviors was investigated by electrochemical workstation. Adhesion was reflected by cross-cut test and pull-off test. Equivalent circuits were used to fit the electrochemical impedance spectrum (EIS). According to experimental results, modified epoxy coatings present good hydrophobicity, good thermal stability at 250 °C with only about 3 % weight loss and the ca. 10 μm modified epoxy coating added with the most hydrophobic nano-silica shows the best anticorrosive performance with impedance of 5.25 × 105 Ω•cm2 (0.01 Hz) at 0 h immersion. The anticorrosive performance of epoxy coating is significantly improved when hydrophobic nano-silica is added into epoxy matrix. Adding hydrophobic nano-silica can effectively prolong the diffusion path of water-soluble corrosive medium and the hydrophobicity is able to retard the diffusion of water.
- Subjects :
- Materials science
Carbon steel
General Chemical Engineering
02 engineering and technology
engineering.material
010402 general chemistry
01 natural sciences
Corrosion
Contact angle
chemistry.chemical_compound
Materials Chemistry
Thermal stability
Trimethylolpropane
Composite material
Organic Chemistry
Epoxy
021001 nanoscience & nanotechnology
0104 chemical sciences
Surfaces, Coatings and Films
chemistry
visual_art
Diethylenetriamine
visual_art.visual_art_medium
engineering
Wetting
0210 nano-technology
Subjects
Details
- ISSN :
- 03009440
- Volume :
- 151
- Database :
- OpenAIRE
- Journal :
- Progress in Organic Coatings
- Accession number :
- edsair.doi...........a9b56a78bc9cb0de750f154cfdc04231