ChemInform Abstract: Remote Chiral Induction in the Thio-Claisen Rearrangement of Bicyclic Thiolactams

Authors :: Daniel J. Watson
Charles M. Lawrence
Albert I. Meyers
Source :: ChemInform. 31
Publication Year :: 2010
Publisher :: Wiley, 2010.
Abstract: A remote steric effect in the bicyclic lactam oxazolidine ring has been shown to affect the stereochemical outcome in the thio-Claisen rearrangement taking place in the piperidone ring.

Subjects :: Claisen rearrangement
Steric effects
Oxazolidine
chemistry.chemical_compound
Bicyclic molecule
Chemistry
Stereochemistry
Lactam
Thio
General Medicine
Ring (chemistry)
Chiral induction

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