Second excited singlet state emission spectroscopy of thiocarbonyls. I. Thiophosgene

Authors :: D.J. Clouthier
A. R. Knight
P.A. Hackett
Ronald P. Steer
Source :: Chemical Physics. 48:1-11
Publication Year :: 1980
Publisher :: Elsevier BV, 1980.
Abstract: Well resolved emission spectra have been recorded after dye laser excitation of low-lying vibronic levels in the B ( 1 A 1 ) state of Cl 2 CS. The effects of substrate pressure, added SF 6 and excitation wavelength on the spectra are reported. A Franck-Condon analysis suggests that the excited state CS bond length is 0.5 A longer than in the ground state.

Subjects :: Bond length
Thiophosgene
chemistry.chemical_compound
Dye laser
chemistry
Excited state
General Physics and Astronomy
Emission spectrum
Physical and Theoretical Chemistry
Atomic physics
Ground state
Spectral line
Excitation

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