ChemInform Abstract: Tin(IV) Chloride Catalyzed Cycloaddition Reactions Between 3-Ethoxycyclobutanones and Allylsilanes

Authors :: Jun-ichi Matsuo
Shun Sasaki
Takaya Hoshikawa
Hiroyuki Ishibashi
Source :: ChemInform. 41
Publication Year :: 2010
Publisher :: Wiley, 2010.
Abstract: Formal [4 + 2] cycloaddition between various 3-ethoxycyclobutanones and allyltrialkylsilanes proceeded to give 3-ethoxy-5-[(trialkylsilyl)methyl]cyclohexan-1-ones by catalysis with tin(VI) chloride. The use of allyl-tert-butyldiphenylsilane induced 1,5-hydride transfer, which gave 2-[3-(tert-butyldiphenylsilyl)propyl]-6-methyltetrahydro-4-pyrones.

Subjects :: chemistry.chemical_compound
chemistry
medicine
chemistry.chemical_element
Tin(IV) chloride
General Medicine
Tin
Medicinal chemistry
Chloride
Cycloaddition
Catalysis
medicine.drug

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