Radiation-induced changes in the electrical properties of carbon filled PVDF thick films

The electrical properties of PVDF thick film capacitors under gamma radiation are investigated. To increase the conductivity of the films, they were filled with 4 and 6 wt.% of carbon, which is close to the percolation threshold. Screen-printing was used for film fabrication. All films were exposed to a disk-type 137 Cs source with an activity of 370 kBq. Changes in I – V characteristics were measured after each exposure dose. A tenfold increase in the values of current was recorded after a dose of 228 μGy for C-PVDF films with a thickness of 23.97 μm and 6 wt.% carbon doping. A higher dose of 342 μGy resulted a decrease in the values of current. Thicker films showed an increase in the values of current with irradiation to a dose of 798 μGy. PVDF + carbon system has potential applications in low-dose radiation dosimetry. The high current induced by radiation caused heating and electroforming of the device, due to the metal inclusions from the Ag contact material. It was noticed that as-printed films of 23.97 μm in thickness, tend to electroform at about 12 V, whereas films irradiated with 171 μGy showed a strong electroforming effect at a lower voltage of 5 V. For that reason, proper design of dosimetry systems is essential to eliminate such effects. Gamma radiation sensitivity of counterpart PVDF thick films with 4 wt.% carbon doping was studied via capacitance-dose measurements in real time, since these samples were less conductive. Irradiation of this sensor with doses from 1.15 to 2.5 mGy caused a considerable monotonic increase in the values of its capacitance from 2.92 to 12.37 pF. Accordingly, sensors with 4 wt.% of carbon could sustain higher radiation doses, but had poor sensitivity to radiation of lower level.