Back to Search Start Over

Liquid–Liquid Extraction of Cyclopentanone from Aqueous Solution with Methylcyclohexane or Propyl Acetate at Different Temperatures

Authors :
Saisai Zhou
Qingsong Li
Bing Jia
Midong Shi
Liping Wang
Hai Liu
Source :
Journal of Chemical & Engineering Data. 63:2653-2659
Publication Year :
2018
Publisher :
American Chemical Society (ACS), 2018.

Abstract

Our research extends the knowledge into the liquid–liquid extraction regarding ternary mixtures of water + cyclopentanone + extractants (methylcyclohexane and propyl acetate) at 308.2, 318.2, and 328.2 K and 101.3 kPa. The extracting capabilities of the selected extractants were explored when it came to the distribution coefficient and selectivity on the basis of the liquid–liquid equilibrium values, while the consistency of the dependability of the tie-line values was corroborated utilizing both the Bachman and Hand empirical equations. In addition, the binary interaction energy parameters of the compounds were achieved by two classic activity coefficient models (i.e., NRTL and UNIQUAC); satisfactory results were yielded with all the fitting root-mean square deviations (rmsd %) ≤ 0.71.

Details

ISSN :
15205134 and 00219568
Volume :
63
Database :
OpenAIRE
Journal :
Journal of Chemical & Engineering Data
Accession number :
edsair.doi...........a7c1bbf155bc4969bd0910ae4b481774
Full Text :
https://doi.org/10.1021/acs.jced.7b01109