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Liquid–Liquid Extraction of Cyclopentanone from Aqueous Solution with Methylcyclohexane or Propyl Acetate at Different Temperatures
- Source :
- Journal of Chemical & Engineering Data. 63:2653-2659
- Publication Year :
- 2018
- Publisher :
- American Chemical Society (ACS), 2018.
-
Abstract
- Our research extends the knowledge into the liquid–liquid extraction regarding ternary mixtures of water + cyclopentanone + extractants (methylcyclohexane and propyl acetate) at 308.2, 318.2, and 328.2 K and 101.3 kPa. The extracting capabilities of the selected extractants were explored when it came to the distribution coefficient and selectivity on the basis of the liquid–liquid equilibrium values, while the consistency of the dependability of the tie-line values was corroborated utilizing both the Bachman and Hand empirical equations. In addition, the binary interaction energy parameters of the compounds were achieved by two classic activity coefficient models (i.e., NRTL and UNIQUAC); satisfactory results were yielded with all the fitting root-mean square deviations (rmsd %) ≤ 0.71.
- Subjects :
- Activity coefficient
UNIQUAC
Chemistry
General Chemical Engineering
Analytical chemistry
02 engineering and technology
General Chemistry
021001 nanoscience & nanotechnology
Cyclopentanone
Propyl acetate
Partition coefficient
chemistry.chemical_compound
020401 chemical engineering
Liquid–liquid extraction
Non-random two-liquid model
0204 chemical engineering
Methylcyclohexane
0210 nano-technology
Subjects
Details
- ISSN :
- 15205134 and 00219568
- Volume :
- 63
- Database :
- OpenAIRE
- Journal :
- Journal of Chemical & Engineering Data
- Accession number :
- edsair.doi...........a7c1bbf155bc4969bd0910ae4b481774
- Full Text :
- https://doi.org/10.1021/acs.jced.7b01109