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Synthesis and Crystal Structure of Tetrabutylammonium 4-(2-Bromothiophene-5-Sulfanilamide)-Benzoate
- Source :
- Journal of Chemical Crystallography. 40:884-887
- Publication Year :
- 2010
- Publisher :
- Springer Science and Business Media LLC, 2010.
-
Abstract
- Tetrabutylammonium 4-(2-bromothiophene-5-sulfanilamide)-benzoate crystallizes in C2/C lattice with a = 18.3389(17), b = 16.540(16), c = 15.8280(15) A, β = 116.959(2), V = 4279.5(7) A3, Z = 4, and R = 0.0560. In the structure a very short centrosymmetric hydrogen bond and C=O···Br halogen bond interactions, together with N–H···O and C–H···O hydrogen bonds give a three-dimensional network. A extremely short O–H···O hydrogen bond is observed between the two neighboring 4-(2-bromothiophene-5-sulfanilamide)-benzoates. The H atom is fixed at the crystallographic inversion center and bridges the two benzoates to form an anion dimer. Halogen bonds also aid in forming the interest structure in crystal.
Details
- ISSN :
- 15728854 and 10741542
- Volume :
- 40
- Database :
- OpenAIRE
- Journal :
- Journal of Chemical Crystallography
- Accession number :
- edsair.doi...........a74f36187523c54a8d47667dd6250da2