Enhanced thermionic emission of mayenite electride composites in an Ar glow discharge plasma

Mayenite electride has attracted increasing research interests because of its unique electronic properties. The thermionic emission behavior of the mayenite electride is relatively unknown. Previous studies revealed that mayenite electride exhibited a bare work function ranged from 2.1–2.6 eV when the thermionic emission was tested in vacuum, and enhanced emission currents could be achieved by applying a super-high external electric field. In this paper, the thermionic emission behavior and the corresponding effective work function of two types of mayenite electride based composites, mayenite electride-titanium and mayenite electride-carbon, were investigated in an Ar glow discharge plasma at elevated temperatures (400–1000 K) without applying a high external electric field, which is critical for the application in electric propulsion and other aerospace apparatus, yet never had been done before. During the testing, the thermal equilibrium process and plasma sheath expansion were observed. The effective work function of the two mayenite electride composites were determined as a function of temperature. The Rasor-Warner model was applied to determine the bare work function and adsorption-site density of the mayenite electride based composites. Results suggested that the adsorption of Ar ions led to the enhanced thermionic emission (~30 A/m2 at 985 K) and low effective work functions (0.9–2.2 eV) of mayenite electride based composites, without the need of applying high electric fields. Our findings will pave the ways for the application of mayenite electride and its composites as the thrust cathode materials for electric propulsion where plasma is present.