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PdII insertion-triggered meso-carbon extrusion of N-fused pentaphyrin to form N-fused sapphyrin PdII complexes
- Source :
- Chemical Communications. 57:3034-3037
- Publication Year :
- 2021
- Publisher :
- Royal Society of Chemistry (RSC), 2021.
-
Abstract
- meso-Carbon extrusion of N-fused [22]pentaphyrin(1.1.1.1.1) occurred upon its PdII complexation, giving N-fused [22]pentaphyrin (1.1.1.1.0) ([22]sapphyrin) PdII complexes 5 and 6 as 22π aromatic compounds. Oxidation of 5 with DDQ and Sc(OTf)3 gave directly C–N linked dimer 7.
Details
- ISSN :
- 1364548X and 13597345
- Volume :
- 57
- Database :
- OpenAIRE
- Journal :
- Chemical Communications
- Accession number :
- edsair.doi...........a596160fd813b1d009c8e95b2caa4065