Transannular diels-alder reaction of trans-trans-cis 15-membered macrocyclic trienes. Evidence for asynchronous transition state

Authors :: Dennis G. Hall
Renate Müller
Pierre Deslongchamps
Source :: Tetrahedron Letters. 33:5221-5224
Publication Year :: 1992
Publisher :: Elsevier BV, 1992.
Abstract: The transannular Diels-Alder reaction of trans-trans-cis 15-membered macrocyclic trienes 1, 6 , and 7 leading to A.B.C.[6.6.7] tricyclic compounds is described.

Subjects :: Chemistry
Stereochemistry
Organic Chemistry
Drug Discovery
Stereoselectivity
Lewis acids and bases
Thermal reaction
Biochemistry
Cis–trans isomerism
Diels–Alder reaction
Catalysis

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