Back to Search
Start Over
Three metal complexes based on tetrazolyl ligands: Hydrothermal syntheses, crystal structures, and fluorescence properties
- Source :
- Russian Journal of Coordination Chemistry. 42:789-796
- Publication Year :
- 2016
- Publisher :
- Pleiades Publishing Ltd, 2016.
-
Abstract
- Three new complexes based on 1-tetrazole-4-imidazole-benzene (Tibz), namely, [Cd(Tibz)2(H2O)2]n (I), [Mn(Tibz)2(H2O)4] · 2H2O (II) and [Co(Tibz)2(H2O)4] · 2H2O (III) have been synthesized through hydrothermal method and structurally characterized by element analyses, IR spectroscopy and single-crystal X-ray diffraction analyses (CIF files CCDC nos. 1443867 (I), 1443868 (II), 1443869 (III)). Single-crystal X-ray diffraction reveals that complex I is a 1D double-chain architecture, II and III are both mononuclear complexes. The results of single-crystal X-ray diffraction analyses indicate that the hydrogen bond and π··· π stacking exist in the complexes, which make great contribution to the stabilities of complexes I–III. The fluorescent properties of these complexes have also been studied in the solid state at room temperature.
- Subjects :
- Diffraction
Chemistry
Hydrogen bond
General Chemical Engineering
Stacking
Infrared spectroscopy
General Chemistry
Crystal structure
010402 general chemistry
010403 inorganic & nuclear chemistry
01 natural sciences
Fluorescence
Hydrothermal circulation
0104 chemical sciences
Metal
Crystallography
visual_art
visual_art.visual_art_medium
Subjects
Details
- ISSN :
- 16083318 and 10703284
- Volume :
- 42
- Database :
- OpenAIRE
- Journal :
- Russian Journal of Coordination Chemistry
- Accession number :
- edsair.doi...........a22b16fda32c9f4d4f3e476ca5f92004