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Investigating the Influence of Resonant Bonding on the Optical Properties of Phase Change Materials (GeTe)xSnSb2Se4
- Source :
- Chemistry of Materials. 29:9320-9327
- Publication Year :
- 2017
- Publisher :
- American Chemical Society (ACS), 2017.
-
Abstract
- Thin film samples of Ge9SnSb2Te9Se4, Ge4.5SnSb2Te4.5Se4, Ge2.5SnSb2Te2.5Se4, and GeSnSb2TeSe4 were prepared via co-sputtering of GeTe and SnSb2Se4 and compared to the well-investigated phase change material GeTe. All samples were obtained in an amorphous state. Temperature-dependent in situ X-ray diffraction experiments reveal a crystallization temperature that increases with an increasing SnSb2Se4 content, leading to a higher stability of the amorphous phase. The electrical contrast between the amorphous and metastable crystalline state investigated via the van der Pauw method is as large as 4 orders of magnitude up to a 4.5:1 GeTe:SnSb2Se4 ratio. Increasing the SnSb2Se4 content leads to a decrease in the electrical contrast. Investigations of the samples by applying Fourier transform infrared spectroscopy and variable incident angle spectroscopic ellipsometry show that the optical properties of the amorphous phase are not affected by changes in stoichiometry. In striking contrast, the impact of SnSb2Se4...
- Subjects :
- 010302 applied physics
Diffraction
Materials science
Orders of magnitude (temperature)
General Chemical Engineering
Analytical chemistry
02 engineering and technology
General Chemistry
021001 nanoscience & nanotechnology
01 natural sciences
Amorphous solid
Crystallography
Van der Pauw method
Metastability
0103 physical sciences
Materials Chemistry
Thin film
Fourier transform infrared spectroscopy
0210 nano-technology
Stoichiometry
Subjects
Details
- ISSN :
- 15205002 and 08974756
- Volume :
- 29
- Database :
- OpenAIRE
- Journal :
- Chemistry of Materials
- Accession number :
- edsair.doi...........a2100a27b0fb127a3c643f95a8bd624d