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4-(N,N-Di-p-tolylamino)benzaldehydeN′,N′-diphenylhydrazone

Authors :
Shi-Rong Wang
Xiang-Gao Li
De-Shun Xu
Li-Li He
Source :
Acta Crystallographica Section E Structure Reports Online. 62:o685-o686
Publication Year :
2006
Publisher :
International Union of Crystallography (IUCr), 2006.

Abstract

The title compound, (p-MeC6H4)2NC6H4CH=NNPh2 or C33H29N3, was synthesized by the reaction of 4-(di-p-tolyl­amino)benzaldehyde and 1,1-diphenyl­hydrazine. The mol­ecule is the trans isomer with respect to the hydrazone double bond. The central NC6H4CH=N—N fragment is planar within 0.11 A. The planes of the p-tolyl rings and one of the hydrazone phenyl rings form substantial dihedral angles (>60°) with the central plane of the mol­ecule, whereas the second hydrazone phenyl ring is much closer to the central plane, the dihedral angle being 21.7 (3)°.

Details

ISSN :
16005368
Volume :
62
Database :
OpenAIRE
Journal :
Acta Crystallographica Section E Structure Reports Online
Accession number :
edsair.doi...........a1241a1db0529541852e38ef30fce93a
Full Text :
https://doi.org/10.1107/s1600536806001930