Back to Search
Start Over
Depression of proton conductivity in recast NafionĀ® film measured on flat substrate
- Source :
- Journal of Power Sources. 189:994-998
- Publication Year :
- 2009
- Publisher :
- Elsevier BV, 2009.
-
Abstract
- The proton conductivity of recast Nafion® thin films in the lateral direction (parallel to the interface) was measured in humidified atmospheres. The conductivity decreased with a decrease in the thickness of the film: e.g., the conductivity of a film with a thickness of about 100 nm was about an order of magnitude less than that of the bulk material. The dependence of the conductivity on temperature was also measured, and a thinner film showed a higher apparent activation energy for conduction. Since both the conductivity and the apparent activation energy for conduction were affected by the thickness, these phenomena may be due to an intrinsic change in the material. Based on the fact that the apparent activation energy for conduction in the bulk membrane under dry conditions is high, the high apparent activation energy for conduction in thin films may be due to the hindrance of water adsorption.
- Subjects :
- Renewable Energy, Sustainability and the Environment
Analytical chemistry
Energy Engineering and Power Technology
Proton exchange membrane fuel cell
Activation energy
Conductivity
Thermal conduction
chemistry.chemical_compound
chemistry
Nafion
Ionic conductivity
Electrical and Electronic Engineering
Physical and Theoretical Chemistry
Thin film
Composite material
Order of magnitude
Subjects
Details
- ISSN :
- 03787753
- Volume :
- 189
- Database :
- OpenAIRE
- Journal :
- Journal of Power Sources
- Accession number :
- edsair.doi...........a0d1044b00b2e2e3d0892a2bb6f16732