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Base-promoted selective β-fragmentation of homoallylamines

Authors :
Weixun Li
Jianhong Gan
Renhua Fan
Source :
Tetrahedron Letters. 51:4275-4277
Publication Year :
2010
Publisher :
Elsevier BV, 2010.

Abstract

A selective β-fragmentation of homoallylamines with the combination of iodobenzene diacetate, iodine, and sodium acetate is reported. The desired carbon–carbon bond cleavage proceeded via a radical β-scission pathway under mild conditions with good functional group tolerance.

Subjects

Subjects :
chemistry.chemical_classification
Base (chemistry)
Organic Chemistry
Iodobenzene
chemistry.chemical_element
Iodine
Biochemistry
Medicinal chemistry
chemistry.chemical_compound
chemistry
Drug Discovery
Functional group
Fragmentation (cell biology)
Sodium acetate
Bond cleavage

Details

ISSN :
00404039
Volume :
51
Database :
OpenAIRE
Journal :
Tetrahedron Letters
Accession number :
edsair.doi...........a08189c5e7268fd4d69f23a32fc500fc
Full Text :
https://doi.org/10.1016/j.tetlet.2010.06.031
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