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A Convenient Method for the Synthesis of Alkenes from Vic-diols via Cyclic Sulfates with Magnesium Iodide
- Source :
- Synthetic Communications. 28:871-877
- Publication Year :
- 1998
- Publisher :
- Informa UK Limited, 1998.
-
Abstract
- Reaction of cyclic sulfates of vic-diols with magnesium iodide in acetonitrile produced the corresponding olefins in excellent isolated yields at room temperature. Cyclic sulfates of trans-diols gave trans-alkenes exclusively. Cyclic sulfates of cis-diols gave a mixture of cis- and trans- alkenes. However, the cyclic sulfate of cyclic cis-diol afforded the corresponding cis-alkene only.
Details
- ISSN :
- 15322432 and 00397911
- Volume :
- 28
- Database :
- OpenAIRE
- Journal :
- Synthetic Communications
- Accession number :
- edsair.doi...........9fbc2fc65b9b882ada4ab7bc2f7ac857