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Intermolecular cobalt-mediated [2 + 2 + 2]cycloadditions : regiospecific one-step construction of bicyclic dienes from α,ω-enynes and alkynes

Authors :
K. Peter C. Vollhardt
Joseph A. King
Chu-An Chang
Source :
J. Chem. Soc., Chem. Commun.. :53-55
Publication Year :
1981
Publisher :
Royal Society of Chemistry (RSC), 1981.

Abstract

α,ω-Enynes are co-cyclised with alkynes and stoicheiometric amounts of dicarbonyl(cyclopentadienyl) cobalt to furnish bicyclic-diene cobalt complexes and their free ligands regiospecifically, the former being convertible into the latter by oxidative demetallation.

Details

ISSN :
00224936
Database :
OpenAIRE
Journal :
J. Chem. Soc., Chem. Commun.
Accession number :
edsair.doi...........9f60e2dbc4e29f9bd8ff6008d9145974
Full Text :
https://doi.org/10.1039/c39810000053