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A two-dimensional cobalt(II) coordination polymer: poly[chloro(μ-imidazole-1,3-diyldiacetato-κ4O:O′:O′′:O′′′)cobalt(II)]

Authors :
Hui Zhao
Shan Gao
Li-Hua Huo
Xian-Fa Zhang
Source :
Acta Crystallographica Section E Structure Reports Online. 62:m3359-m3361
Publication Year :
2006
Publisher :
International Union of Crystallography (IUCr), 2006.

Abstract

In the title coordination polymer, [Co(IDA)Cl]n (IDA− is the imidazolyl-1,3-diyldiacetate anion, C7H7N2O4), each Co2+ cation has an octa­hedral geometry, defined by four O atoms from four different IDA− anions and two Cl− anions. The IDA− anion serves as a bridging ligand to link the Co2+ cations into a two-dimensional layer structure. The Co atom lies on a centre of symmetry. The Cl atom and one CH group of the imidazole ring lie on twofold rotation axes.

Details

ISSN :
16005368
Volume :
62
Database :
OpenAIRE
Journal :
Acta Crystallographica Section E Structure Reports Online
Accession number :
edsair.doi...........9f1a1ccd6837daad1e5f71da3b69b5f6