Spin-state crossover in photo-catalyzed nitrile dihydroboration via Mn-thiolate cooperation

Authors :: Matthew R. Elsby
Changjin Oh
Mina Son
Scott Y. H. Kim
Mu-Hyun Baik
R. Tom Baker
Source :: Chemical Science. 13:12550-12559
Publication Year :: 2022
Publisher :: Royal Society of Chemistry (RSC), 2022.
Abstract: The role of a phosphine-free SNS-pincer ligand in metal–ligand cooperative hydroboration catalysis was investigated. The bifunctional thiolate donor and spin-state change to high-spin Mn are crucial to accessing low-energy activation barriers.

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