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Reactions of bimetallic group VI complexes
- Source :
- Journal of Organometallic Chemistry. 249:127-135
- Publication Year :
- 1983
- Publisher :
- Elsevier BV, 1983.
-
Abstract
- Triphenylphosphine and trimethylphosphite react with [(C5H5)(OC)2M(μ-SMe)M′(CO)5] (M, M′ = Mo, W) (II) to give [(C5H5)(OC)2)LM(μ-SMe)M′(CO)5] which on heating revert to II. On prolonged heating [(C5H5)(OC)2Mo(μ-SMe)W(CO)4}P(OMe)3}] is formed. [(C5H5)(OC)3W(μ-SMe)W(CO)5] reacts with I2 to give [(C5H5)(OC)2W(μ-SMe)(μ-I)W(CO)3I] for which the crystal structure has been determined.
Details
- ISSN :
- 0022328X
- Volume :
- 249
- Database :
- OpenAIRE
- Journal :
- Journal of Organometallic Chemistry
- Accession number :
- edsair.doi...........9ecc653aa87914d774a9f8146ac66f33