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Thermally Stable Chromium(III) η3-Allyl Complexes. Direct Structural Comparison of Neutral Chromium(II) and Cationic Chromium(III) η3-Allyl Redox Isomers

Authors :
Jeffrey M. Stryker
David W. Norman
Robert McDonald
Source :
Organometallics. 24:4461-4467
Publication Year :
2005
Publisher :
American Chemical Society (ACS), 2005.

Abstract

The first thermally stable chromium(III) η3-allyl complexes have been prepared. Oxidation of neutral cyclopentadienylchromium(II) dicarbonyl η3-allyl, η3-crotyl, and η3-cyclohexenyl complexes 1−3, ...

Details

ISSN :
15206041 and 02767333
Volume :
24
Database :
OpenAIRE
Journal :
Organometallics
Accession number :
edsair.doi...........9de7a48b9b34083e336f7b5abcda0fb2
Full Text :
https://doi.org/10.1021/om050415z