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Enantioselective total synthesis of idesolide via NaHCO3-promoted dimerization
- Source :
- Tetrahedron. 66:4965-4969
- Publication Year :
- 2010
- Publisher :
- Elsevier BV, 2010.
-
Abstract
- The enantioselective total synthesis of idesolide has been accomplished in 20% overall yield from a known allylic alcohol by a nine-step sequence involving the Sharpless asymmetric epoxidation as the source of chirality and an efficient NaHCO 3 -promoted dimerization of the monomeric form of idesolide as the key transformation.
Details
- ISSN :
- 00404020
- Volume :
- 66
- Database :
- OpenAIRE
- Journal :
- Tetrahedron
- Accession number :
- edsair.doi...........9d4919e8738fbb80b662befe815a88e2