Reactivity of Dinuclear Rhodium(I) Macrocycles Formed via the Weak-Link Approach

Authors :: Charlotte L. Stern
Maxim V. Ovchinnikov
Junpei Kuwabara
Chad A. Mirkin
Source :: Organometallics. 27:789-792
Publication Year :: 2008
Publisher :: American Chemical Society (ACS), 2008.
Abstract: The reaction of a macrocyclic Rh(I) complex having hemilabile PO ligands with Cl− results in Rh−O bond breakage and yields a Cl-bridged tetranuclear Rh(I) complex, which was characterized by a single-crystal X-ray diffraction study. Reactivity of the complex with CO and halide abstracting agents is described.

Subjects :: Inorganic Chemistry
Chemistry
Organic Chemistry
Polymer chemistry
Halide
chemistry.chemical_element
Reactivity (chemistry)
Physical and Theoretical Chemistry
Weak-Link Approach
Photochemistry
Rhodium

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