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A systematic approach of using green solvent for the extraction of Pb (II) from aqueous solution
- Source :
- International Journal of Environmental Science and Technology. 19:1369-1382
- Publication Year :
- 2021
- Publisher :
- Springer Science and Business Media LLC, 2021.
-
Abstract
- In this article, the extraction behavior of halogen-free ionic liquid, 1-butyl-3-methylimidazolium octyl sulfate, was investigated in the separation of lead from the aqueous solution. Experimental parameters include time, impact of pH, feed concentration, amount of ionic liquid, ionic strength, and temperature were optimized for the evaluation of the lead extraction. From the optimum conditions, it was emanated that the maximum extraction efficiency of lead was 97% with the feed concentration of 10 ppm in an equilibrium time of 60 min at the pH of 5 and 2 g of the ionic liquid, respectively. Furthermore, the extraction results revealed that the higher efficiency was achieved without the addition of salt and that the extraction process was spontaneous and endothermic in nature. The metal complexation was formed by the exchange of ionic liquid anion to the aqueous phase, and thereby, the extraction mechanism was proposed. The ionic liquid in the organic phase was stripped using sodium sulfate as a stripping agent. FTIR analysis confirmed the recoverable ionic liquid and effectively reused it five times in the course of extraction. From the analysis, it was authenticated that the ionic liquid, 1-butyl-3-methylimidazolium octyl sulfate, was an effective extractant for the elimination of lead (II) and could be employed for the tertiary treatment of industrial wastes.
- Subjects :
- chemistry.chemical_classification
Environmental Engineering
Aqueous solution
Inorganic chemistry
Extraction (chemistry)
Aqueous two-phase system
Salt (chemistry)
010501 environmental sciences
01 natural sciences
Solvent
chemistry.chemical_compound
chemistry
Ionic strength
Ionic liquid
Sodium sulfate
Environmental Chemistry
General Agricultural and Biological Sciences
0105 earth and related environmental sciences
Subjects
Details
- ISSN :
- 17352630 and 17351472
- Volume :
- 19
- Database :
- OpenAIRE
- Journal :
- International Journal of Environmental Science and Technology
- Accession number :
- edsair.doi...........9c55d4ee7d83175278e90834b5f234e3