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Thermally activated delayed fluorescent emitters based on 3-(phenylsulfonyl)pyridine
- Source :
- Chemical Physics Letters. 771:138474
- Publication Year :
- 2021
- Publisher :
- Elsevier BV, 2021.
-
Abstract
- 3-(Phenylsulfonyl)pyridine (PSP), an unreported acceptor, is used to construct two thermally activated delayed fluorescent materials (TADF), PSPP and PSPBP, with rigid PXZ as donor in 3-position or 3, 5-position of PSP. Both PSPP and PSPBP have large twisted structure due to highly steric hindrance, resulting in small Ξ”EST. Simultaneously, the frontier molecular orbitals of PSPP and PSPBP show limited spatial overlap, which improve photoluminescence quantum yields. Both emitters have distinct TADF performance. The OLEDs based on these emitters exhibit good photoelectric properties. This work enriches the acceptor selection scope and possesses crucial significance to developing new TADF molecules.
- Subjects :
- Steric effects
Materials science
Photoluminescence
General Physics and Astronomy
02 engineering and technology
010402 general chemistry
021001 nanoscience & nanotechnology
Photochemistry
01 natural sciences
Fluorescence
Acceptor
0104 chemical sciences
chemistry.chemical_compound
chemistry
Pyridine
OLED
Molecule
Molecular orbital
Physical and Theoretical Chemistry
0210 nano-technology
Subjects
Details
- ISSN :
- 00092614
- Volume :
- 771
- Database :
- OpenAIRE
- Journal :
- Chemical Physics Letters
- Accession number :
- edsair.doi...........9be45f645fd3a87d64c4bfa9f4829066