Phase Transition and Ferroelectricity of Two Perovskite-Like Mn(II) Metal–Organic Frameworks Tuned by Phosphonium Cations and Dicyanamide Ligand

Authors :: Yu-Qing Wu
Zhao-Xi Wang
Xiang He
Jia-Yao Zhang
Hong-Ling Cai
Ming-Xing Li
Source :: Crystal Growth & Design. 21:6245-6253
Publication Year :: 2021
Publisher :: American Chemical Society (ACS), 2021.
Abstract: Two metal–organic frameworks, [Me(n-Bu)3P][Mn(dca)3] (1) and (Et4P)[Mn(dca)3] (2) (dca: N(CN)2–, dicyanamide), exhibit perovskite-like (ABX3) three-dimensional structures. Two phosphonium cations o...

Subjects :: Phase transition
Materials science
Ligand
General Chemistry
Condensed Matter Physics
Ferroelectricity
chemistry.chemical_compound
Crystallography
chemistry
General Materials Science
Metal-organic framework
Phosphonium
Dicyanamide
Perovskite (structure)

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