Back to Search
Start Over
Formation of Tantalum 'Tuck-in' Complexes by Activation of Methyl C−H Bonds in Pentamethylcyclopentadiene Groups by Carbazole Ligation
- Source :
- Organometallics. 18:3579-3583
- Publication Year :
- 1999
- Publisher :
- American Chemical Society (ACS), 1999.
-
Abstract
- The reaction of [Cp*TaCl4] with the potassium salt of carbazole (cbK, >3 equiv) in hydrocarbon solvents leads to the species [(C5Me4CH2)Ta(cb)2Cl] (1), in which one of the ring methyl C−H bonds of ...
- Subjects :
- chemistry.chemical_classification
Chemistry
Carbazole
Potassium
Organic Chemistry
Pentamethylcyclopentadiene
Tantalum
Salt (chemistry)
chemistry.chemical_element
Ring (chemistry)
Medicinal chemistry
Inorganic Chemistry
chemistry.chemical_compound
Hydrocarbon solvents
Organic chemistry
Physical and Theoretical Chemistry
Ligation
Subjects
Details
- ISSN :
- 15206041 and 02767333
- Volume :
- 18
- Database :
- OpenAIRE
- Journal :
- Organometallics
- Accession number :
- edsair.doi...........9ba4c12c93dbc53a9189144680a497b4
- Full Text :
- https://doi.org/10.1021/om990388a