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A Highly Reactive Chromium(V)–Oxo TAML Cation Radical Complex in Electron Transfer and Oxygen Atom Transfer Reactions
- Source :
- ACS Catalysis. 11:2889-2901
- Publication Year :
- 2021
- Publisher :
- American Chemical Society (ACS), 2021.
-
Abstract
- We report the synthesis, characterization, and electron-transfer (ET) oxidation reactivity of a chromium(V)–oxo TAML cation radical complex binding Sc3+ ion, {[CrV(O)(TAML•+)]-Sc3+}3+ (2-Sc). Its p...
Details
- ISSN :
- 21555435
- Volume :
- 11
- Database :
- OpenAIRE
- Journal :
- ACS Catalysis
- Accession number :
- edsair.doi...........9b24632672c00896b2aaced67c0e38de
- Full Text :
- https://doi.org/10.1021/acscatal.1c00079