Back to Search
Start Over
A bimetallic molybdenum (VI) and stannum (IV) catalyst for the transesterification of dimethyl oxalate with phenol
- Source :
- Catalysis Communications. 5:179-184
- Publication Year :
- 2004
- Publisher :
- Elsevier BV, 2004.
-
Abstract
- The transesterification of dimethyl oxalate (DMO) with phenol to methyl phenyl oxalate (MPO) and diphenyl oxalate (DPO) was carried out in liquid phase under facile catalytic conditions. A series of bimetallic, MoO3–SnO2/SiO2, catalysts with various Mo and Sn content were prepared by sequential impregnation of cationic Mo species and cationic Sn complexes using impregnation method. The effects of mass ratio of Mo:Sn, amount of Sn additive, and Mo(Sn) laoding amount on activities of transesterification of dimethyl oxalate with phenol were investigated. The evaluation results showed that MoO3–SnO2/SiO2 catalyst with 14 wt% Mo(Sn) content performed best, giving 74.6% DMO conversion and 99.5% selectivity to MPO and DPO. This new heterogeneous catalyst provided not only an excellent selectivity (99% to MPO and DPO) and high yield of MPO and DPO but also a simple and practical protocol for DPC synthesis.
Details
- ISSN :
- 15667367
- Volume :
- 5
- Database :
- OpenAIRE
- Journal :
- Catalysis Communications
- Accession number :
- edsair.doi...........9b0a89647d6380843dcc9cd3292c286f
- Full Text :
- https://doi.org/10.1016/j.catcom.2004.01.006